Il-Ha Koh1·Yo Seb Kwon1,2·Deok Hyun Moon3·Ju In Ko4·Won Hyun Ji4*
1National Environment Lab. (NeLab),
Seoul 02841, Korea
2Department of Energy and Mineral Resources Engineering, Sejong
University, Seoul 05006, Korea
3Department of Environmental Engineering, Chosun University, Gwangju
61452, Korea
4Institute of Mine Reclamation Technology, Mine Reclamation
Corporation, Gangwon-Do 26464, Korea
고일하1·권요셉1,2·문덕현3·고주인4·지원현4*
1환경기술정책연구원
2세종대학교 에너지자원공학과
3조선대학교 환경공학과
4한국광해관리공단 기술연구소
This study assessed the feasibility of coal mine drainage sludge (CMDS)
as a stabilizing agent for mercury contaminated soil through pot experiments
and batch tests. In the pot experiments with 43 days of lettuce growth, the
bioavailability of mercury in the amended soil and mercury content of the
lettuce were decreased by 46% and 50%, respectively. These results were similar
to those of the soil amended with the sulfide compound (FeS) generally used for
mercury stabilization. Thus, CMDS could be an attractive mercury stabilizer in
terms of industrial by-product recycling. Batch tests were conducted to examine
mercury fractionation including reactions between the soil and acetic acid. The
result showed that some elemental fraction changed to strongly bounded fraction
rather than residual (HgS) fraction. This made it possible to conclude that
mercury adsorption on oxides in CMDS was the major mechanism of stabilization.
Keywords: Mercury, Stabilization, CMDS (coal mine drainage sludge), Bioavailability, Fractionation
2020; 25(1): 53-61
Published on Mar 31, 2020
Institute of Mine Reclamation Technology, Mine Reclamation Corporation, Gangwon-Do 26464, Korea