• Feasibility of Diffusive Gradients in Thin Films for Monitoring Heavy Metals in Groundwater
  • Kyu-Young Shim1, Kwangjin Park2, Seungwoo Lee2, Jongmin Choi2, Subin Choi2, Jinsung An1,3*, Kyoungphile Nam4

  • 1Department of Smart City Engineering, Hanyang University, Ansan 15588, South Korea
    2Daeil Engineering & Consulting Co., LTD
    3Department of Civil and Environmental Engineering, Hanyang University, Ansan 15588, South Korea
    4Department of Civil and Environmental Engineering, Seoul National University, Seoul 08826, South Korea

  • 지하수 내 중금속 모니터링을 위한 diffusive gradients in thin films의 적용 가능성 평가
  • 심규영1·박광진2·이승우2·최종민2·최수빈2·안진성1,3*·남경필4

  • 1한양대학교 ERICA 스마트시티공학과
    2(주)대일이앤씨
    3한양대학교 ERICA 건설환경공학과
    4서울대학교 건설환경공학부

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

References
  • 1. Alakangas, L. J., Mathurin, F. A., & Åström, M. E., 2020, Diverse fractionation patterns of Rare Earth Elements in deep fracture groundwater in the Baltic Shield–Progress from utilisation of Diffusive Gradients in Thin-films (DGT) at the Äspö Hard Rock Laboratory, Geochimica et Cosmochimica Acta, 269, 15-38.
  •  
  • 2. Alotaibi, G. F., & Bukhari, M. A., 2021, Factors influencing bacterial biofilm formation and development, Am. J. Biomed. Sci. Res, 12(6), 617-626.
  •  
  • 3. Bennett, W. W., Teasdale, P. R., Panther, J. G., Welsh, D. T., & Jolley, D. F., 2010, New diffusive gradients in a thin film technique for measuring inorganic arsenic and selenium (IV) using a titanium dioxide based adsorbent, Analytical Chemistry, 82(17), 7401-7407.
  •  
  • 4. Bennett, W. W., Teasdale, P. R., Panther, J. G., Welsh, D. T., & Jolley, D. F., 2011, Speciation of dissolved inorganic arsenic by diffusive gradients in thin films: selective binding of AsIII by 3-mercaptopropyl-functionalized silica gel, Anal. Chem., 83(21), 8293-8299.
  •  
  • 5. Burri, N. M., Weatherl, R., Moeck, C., & Schirmer, M., 2019, A review of threats to groundwater quality in the anthropocene, Science of the Total Environment, 684, 136-154.
  •  
  • 6. Chang, L. Y., Davison, W., Zhang, H., & Kelly, M., 1998, Performance characteristics for the measurement of Cs and Sr by diffusive gradients in thin films (DGT), Analytica Chimica Acta, 368(3), 243-253.
  •  
  • 7. Davison, W., & Zhang, H., 2012, Progress in understanding the use of diffusive gradients in thin films (DGT)–back to basics, Environmental Chemistry, 9(1), 1-13.
  •  
  • 8. Díez, S., & Giaggio, R., 2018, Do biofilms affect the measurement of mercury by the DGT technique? Microcosm and field tests to prevent biofilm growth, Chemosphere, 210, 692-698.
  •  
  • 9. Dunn, R. J. K., Teasdale, P. R., Warnken, J., Jordan, M. A., & Arthur, J. M., 2007, Evaluation of the in situ, time-integrated DGT technique by monitoring changes in heavy metal concentrations in estuarine waters, Environmental Pollution, 148(1), 213-220.
  •  
  • 10. Feng, Z., Zhang, W., & Sun, T., 2021, Effects of seasonal biofouling on diffusion coefficients through filter membranes with different hydrophilicities in natural waters, Science of The Total Environment, 794, 148536.
  •  
  • 11. Gimpel, J., Zhang, H., Hutchinson, W., & Davison, W., 2001, Effect of solution composition, flow and deployment time on the measurement of trace metals by the diffusive gradient in thin films technique, Analytica chimica acta, 448(1-2), 93-103.
  •  
  • 12. Horowitz, A. J., Elrick, K. A., & Colberg, M. R., 1992, The effect of membrane filtration artifacts on dissolved trace element concentrations, Water Research, 26(6), 753-763.
  •  
  • 13. Horowitz, A. J., Lum, K. R., Garbarino, J. R., Hall, G. E., Lemieux, C., & Demas, C. R., 1996, Problems associated with using filtration to define dissolved trace element concentrations in natural water samples, Environmental science & technology, 30(3), 954-963.
  •  
  • 14. Jiménez-Piedrahita, M., Altier, A., Cecilia, J., Puy, J., Galceran, J., Rey-Castro, C., ... & Davison, W., 2017, Extending the use of Diffusive Gradients in Thin Films (DGT) to solutions where competition, saturation, and kinetic effects are not negligible, Analytical Chemistry, 89(12), 6567-6574.
  •  
  • 15. Liu, Y., Wei, L., Deng, H., Hu, S., Xie, X., Luo, D., & Xiao, T., 2023, Hydrogeochemistry of groundwater surrounding a pyrite mine in southern China: Assessment of the diffusive gradients in thin films technique for in situ monitoring, Journal of Hydrology, 622, 129685.
  •  
  • 16. Lucas, A. R., Reid, N., Salmon, S. U., & Rate, A. W., 2014, Quantitative assessment of the distribution of dissolved Au, As and Sb in groundwater using the diffusive gradients in thin films technique, Environmental science & technology, 48(20), 12141-12149.
  •  
  • 17. McMillan, L. A., Rivett, M. O., Tellam, J. H., Dumble, P., & Sharp, H., 2014, Influence of vertical flows in wells on groundwater sampling, Journal of Contaminant Hydrology, 169, 50-61.
  •  
  • 18. Mohammadi, A., Corbett, T., French, A., Lehto, N. J., Hadfield, J., Jarman, P., ... & Hartland, A., 2022, Application of diffusive gradients in thin films for monitoring groundwater quality, ACS ES&T Water, 2(4), 518-526.
  •  
  • 19. Panther, J. G., Teasdale, P. R., Bennett, W. W., Welsh, D. T., & Zhao, H., 2010, Titanium dioxide-based DGT technique for in situ measurement of dissolved reactive phosphorus in fresh and marine waters, Environmental science & technology, 44(24), 9419-9424.
  •  
  • 20. Panther, J. G., Bennett, W. W., Welsh, D. T., & Teasdale, P. R., 2014, Simultaneous measurement of trace metal and oxyanion concentrations in water using diffusive gradients in thin films with a Chelex–Metsorb mixed binding layer, Analytical chemistry, 86(1), 427-434.
  •  
  • 21. Pichette, C., Zhang, H., & Sauvé, S., 2009, Using diffusive gradients in thin-films for in situ monitoring of dissolved phosphate emissions from freshwater aquaculture, Aquaculture, 286(3-4), 198-202.
  •  
  • 22. Price, H. L., Teasdale, P. R., & Jolley, D. F., 2013, An evaluation of ferrihydrite-and Metsorb™-DGT techniques for measuring oxyanion species (As, Se, V, P): Effective capacity, competition and diffusion coefficients, Analytica Chimica Acta, 803, 56-65.
  •  
  • 23. Turner, G. S., Mills, G. A., Bowes, M. J., Burnett, J. L., Amos, S., & Fones, G. R., 2014, Evaluation of DGT as a long-term water quality monitoring tool in natural waters; uranium as a case study, Environmental Science: Processes & Impacts, 16(3), 393-403.
  •  
  • 24. Uher, E., Compère, C., Combe, M., Mazeas, F., & Gourlay-Francé, C., 2017, In situ measurement with diffusive gradients in thin films: effect of biofouling in freshwater, Environ. Res., 24, 13797-13807.
  •  
  • 25. Uher, E., Zhang, H., Santos, S., Tusseau-Vuillemin, M. H., & Gourlay-Francé, C., 2012, Impact of biofouling on diffusive gradient in thin film measurements in water, Anal. Chem., 84(7), 3111-3118.
  •  
  • 26. Wang, R., Jones, K. C., & Zhang, H., 2020, Monitoring organic pollutants in waters using the diffusive gradients in the thin films technique: investigations on the effects of biofouling and degradation, Environ. Sci. Technol, 54(13), 7961-7969.
  •  
  • 27. Warnken, K. W., Zhang, H., & Davison, W., 2006, Accuracy of the diffusive gradients in thin-films technique: diffusive boundary layer and effective sampling area considerations, Anal. Chem., 78(11), 3780-3787.
  •  
  • 28. Zhang, H., & Davison, W., 1995, Performance characteristics of diffusion gradients in thin films for the in situ measurement of trace metals in aqueous solution, Analytical chemistry, 67(19), 3391-3400.
  •  

This Article

  • 2024; 29(4): 12-20

    Published on Aug 30, 2024

  • 10.7857/JSGE.2024.29.4.012
  • Received on Jul 19, 2024
  • Revised on Jul 25, 2024
  • Accepted on Aug 16, 2024

Correspondence to

  • Jinsung An
  • 1Department of Smart City Engineering, Hanyang University, Ansan 15588, South Korea
    3Department of Civil and Environmental Engineering, Hanyang University, Ansan 15588, South Korea

  • E-mail: jsan86@hanyang.ac.kr